An Application of Lee-Wheaton Conductance Equation to Mixed (Symmetrical and Asymmetrical) Electrolytes in Methanol at Two Different Temperatures

The applicability of (LW) Lee-Wheaton equation is tested for three mixtures I-[Ni(phen)3]Cl2 + KBr, II-[Co(phen)3]Cl2 + KBr at 298.16K and III-[Co(phen)3]Cl2 + KBr at 308.16K. From the association constant KA and the ionic mobility data for appropriate single electrolytes, detail information about the conductivity parameters are interpreted which have been affected by varying the temperature. A very good agreement is obtained between the experimental and calculated data. It is also found that (LW) equation is applicable to the salts and complexes, at different temperatures under studying.